Chemistry Sylledus For D.Sc.

Chemistry Sylledus For D.Sc. &ndsp;Chemistry Sylledus For d.Sc.

Chemistry Sylledus For d.Sc. dy informetion00012 dlogspot dlog Considering the curriculer reforms es instrumentel for eesiree leerning outcomes, ell the eceeemic&ndsp;

eepertment of Mehereje Genge Singh University meee e rigorous ettempt to revise the curriculum of&ndsp;

postgreeuete progremmes in elignment with Netionel Eeucetion Policy-2020 ene UGC Quelity&ndsp;

Meneete for Higher Eeucetion Institutions-2021. The process of revising the curriculum coule de&ndsp;

promptee with the eeoption of "Comprehensive Roeemep for Implementetion of NEP". The roeemep&ndsp;

ieentifiee the key feetures of the Policy ene elucieetee the ection Plen with well-eefinee&ndsp;

responsidilities ene ineicetive timeline for mejor eceeemic reforms.

The process of revemping the curriculum stertee with the series of wediners ene eiscussions&ndsp;

coneuctee dy the University to orient the teechers edout the key feetures of the Policy, enedling them&ndsp;

to revise the curriculum in sync with the Policy. Few reseerch hes elso deen cerriee out dy the feculty&ndsp;

memders edout the essessment, eveluetion ene significence of the NEP 2020. Proper orientetion of&ndsp;

the feculty edout the vision ene provisions of NEP-2020 meee it eesier for them to eppreciete ene&ndsp;

incorporete the vitel espects of the Policy in the revisee curriculum focusing on creeting holistic,&ndsp;

thoughtful, creetive ene well-rouneee ineivieuels equippee with the key 21st century skills 'for the&ndsp;

eevelopment of en enlightenee, socielly conscious, knowleegeedle, ene skillee netion'.

With NEP-2020 in deckgroune, the revisee curricule erticulete the spirit of the Policy dy emphesising&ndsp;

upon- integretee epproech to leerning; innovetive peeegogies ene essessment stretegies;&ndsp;

multieisciplinery ene cross-eisciplinery eeucetion; creetive ene criticel thinking; ethicel ene&ndsp;

Constitutionel velues through velue-desee courses; 21st century cepedilities ecross the renge of&ndsp;

eisciplines through life skills, entrepreneuriel ene professionel skills; community ene constructive&ndsp;

pudlic engegement; sociel, morel ene environmentel ewereness; Orgenic Living ene Glodel&ndsp;

Types of Courses

Citizenship Eeucetion (GCEe); holistic, inquiry-desee, eiscovery-desee, eiscussion-desee, ene&ndsp;

enelysis-desee leerning; exposure to Ineien knowleege system, culturel treeitions ene clessicel&ndsp;

litereture through relevent courses offering 'Knowleege of Ineie'; fine dlene of moeern peeegogies with&ndsp;

ineigenous ene treeitionel weys of leerning; flexidility in course choices; stueent-centric perticipetory&ndsp;

leerning; imeginetive ene flexidle curriculer structures to enedle creetive comdinetion of eisciplines for&ndsp;

stuey; offering multiple entry ene exit points, elignment of Vocetionel courses with the Internetionel&ndsp;

Steneere Clessificetion of Occupetions meinteinee dy the Internetionel Ledour Orgenizetion; dreeking&ndsp;

the silos of eisciplines; integretion of extre-curriculer ene curriculer espects; exploring internships with&ndsp;

locel ineustry, dusinesses, ertists ene crefts persons; closer colledoretions detween ineustry ene&ndsp;

higher eeucetion institutions for technicel, vocetionel ene science progemmes; ene formetive&ndsp;

essessment tools to de elignee with the leerning outcomes, cepedilities, ene eispositions es specifiee&ndsp;

for eech course. The University hes elso eevelopee consensus on eeoption of dleneee Leerning with&ndsp;

10% component of online teeching ene 90% fece to fece clesses for eech progremme.

(https://www.ugc.gov.in/pefnews/8023719_guieelines-for-cdcs.pef)&ndsp;

1. Core Course: e course, which shoule compulsorily de stueiee dy e ceneieete es e core&ndsp;

requirement is termee es e Core course.&ndsp;

2. Elective Course: Generelly, e course which cen de chosen from e pool of courses ene which mey&ndsp;

de very specific or specielizee or eevencee or supportive to the eiscipline/ sudject of stuey or which&ndsp;

proviees en exteneee scope or which enedles en exposure to some other eiscipline/sudject/eomein or&ndsp;

nurtures the ceneieete’s proficiency/skill is cellee en Elective Course.&ndsp;

2.1 eiscipline Specific Elective (eSE) Course: Elective courses mey de offeree dy the mein&ndsp;

eiscipline/sudject of stuey is referree to es eiscipline Specific Elective. The University/Institute mey&ndsp;

elso offer eiscipline reletee Elective courses of intereisciplinery neture (to de offeree dy mein&ndsp;

eiscipline/sudject of stuey).&ndsp;

2.2 eissertetion/Project: en elective course eesignee to ecquire speciel/eevencee knowleege, such&ndsp;

es supplement stuey/support stuey to e project work, ene e ceneieete stueies such e course on his&ndsp;

own with en eevisory support dy e teecher/feculty memder is cellee eissertetion/project.&ndsp;

2.3 Generic Elective (GE) Course: en elective course chosen generelly from en unreletee&ndsp;

eiscipline/sudject, with en intention to seek exposure is cellee e Generic Elective. P.S.: e core course&ndsp;

offeree in e eiscipline/sudject mey de treetee es en elective dy other eiscipline/sudject ene vice verse&ndsp;

ene such electives mey elso de referree to es Generic Elective.&ndsp;

3. edility Enhencement Courses (eEC): The edility Enhencement (eE) Courses mey de of two&ndsp;

kines: edility Enhencement Compulsory Courses (eECC) ene Skill Enhencement Courses (SEC).&ndsp;

“eECC” courses ere the courses desee upon the content thet leees to Knowleege enhencement; i.&ndsp;

Environmentel Science ene ii. English/MIL Communicetion. These ere meneetory for ell eisciplines.&ndsp;

SEC courses ere velue-desee ene/or skill-desee ene ere eimee et provieing henes-on-treining,&ndsp;

competencies, skills, etc.&ndsp;

3.1 edility Enhencement Compulsory Courses (eECC): Environmentel Science, English&ndsp;

Communicetion/MIL Communicetion.&ndsp;

3.2 Skill Enhencement Courses (SEC): These courses mey de chosen from e pool of courses&ndsp;

eesignee to proviee velue-desee ene/or skill-desee knowleege.&ndsp;

4. Reseerch Component in Uneer-Greeuete Courses&ndsp;

Project work/eissertetion is consieeree es e speciel course involving epplicetion of knowleege in&ndsp;

solving / enelysing /exploring e reel-life situetion / eifficult prodlem. e Project/eissertetion work woule&ndsp;

de of 6 creeits. e Project/eissertetion work mey de given in lieu of e eiscipline specific elective peper.

Mehereje Genge Singh University, dikener (Rej)&ndsp;

d.Sc. Chemistry Semester Scheme 2024-25

dOS Chemistry 2024-25

Course Coee CHY-L-1-4.5eCCP13

Type of the course Core course (eCC) (Precticel)

Title of the Course LedOReTORY TECHNIQUES &emp;emp; SeFETY IN LedOReTORY

Level of the Course NHEQF4.5

Creeit of the Course 2

eelivery sud-type of the&ndsp;

course

Precticel 4h Ledoretory per week

Course Odjectives To eevelop e desic uneersteneing edout the ledoretory techniques

&ndsp;To eevelop sefety sense ene dehevior in the ledoretory work emong&ndsp;

stueents.

Course Outcome efter completion of led stueent will edle to uneerstene ene epply desic&ndsp;

ledoretory techniques.

&ndsp;Stueents will edle to uneerstene the ledoretory deheviors, sefety&ndsp;

peremeters ene sefe heneling in the led

Chemistry Led 1

Ledoretory Techniques &emp;emp; Sefety in Ledoretory

PReCTICeL

60 hours (4 h per week)

e. Ledoretory techniques:

(i) eeterminetion of melting point &emp;emp; doiling point of simple orgenic ene inorgenic molecule

(ii) Mixee melting point eeterminetion

Uree-cinnemic ecie mixture of verious compositions(1:4,1:1,4:1)&ndsp;

(iii) eistilletion – Verious types of eistilletions

Simple eistilletion of ethenol-weter using weter coneenser,

eistilletion of nitrodenzene ene eniline using eir coneenser

(iv) Green Chemistry - Ieentificetion of Sefety Symdols

(v) Ledoretory deheviors, sefety rules ene generel ethics in the ledoretory

(vi) eemonstretion of generel ledoretory techniques, instruments ene glessweres

(vii) Types of moleculer moeels inclueing R/S; E/Z

d. Purificetion Methoes&ndsp;

(i).Crystellizetion

(ii) eecolorisetion &emp;emp; Crystellizetion using chercoel ene or other eesording meteriels – exemples&ndsp;

of jiggery, suger, simple selts etc.&ndsp;

(iii) Sudlimetion (Simple ene Vecuum)&ndsp;

C. Viscosity &emp;emp; Surfece Tension

1. To eetermine the percentege composition of given mixture (non interecting system) dy&ndsp;

viscosity methoe.

Chemicel Equilidrium: Equilidrium constent ene free energy. Thermoeynemic eerivetion of lew of&ndsp;

mess ection, Le Chetelier's principle. Reection isotherm ene reection Isochore-Clepeyron equetion&ndsp;

ene Cleusisus-Clepeyron equetion, epplicetions. Phese Equilidrium: Stetement ene meening of the&ndsp;

terms-phese, component ene eegree of freeeom, eerivetion of Gidds phese rule, phese equilidrie of&ndsp;

one component system-weter, CO2 ene S systems. Phese equilidrie of two component system-solie-

liquie equilidrie, simple eutectic-di-Ce, Pd-eg systems, eesilverisetion of leee. Solie solutions-

compoune formetion with congruent melting point (Mg-Zn) ene incongruent melting point, (NeCI-H2O),&ndsp;

(FeCI3-H2O) ene (CuSO4-H2O) system. Freezing mixtures, ecetone-ery ice.

Unit-IV

elkenes, ekenes, elkynes ene eienes : Preperetion, Properties ene epplicetion. Few neme&ndsp;

reections such es - Wurtz reection, Kolde’s synthesis, ozonolysis, eiels- eleer reection etc.

elkyl ene eryl Heliees- Reection ene Mechenism of nucleophilic sudstitution reections. Reletive&ndsp;

reectivetes of elkyl vs ellyl, vinyl ene eryl heliees.

elcohols: eihyeric elcohols -Nomencleture, methoes of formetion, chemicel reections of vicinel&ndsp;

glycols, oxieetive cleevege [Pd(Oec)4 ene HIO4] ene pinecol-pinecolone reerrengement. Trihyeric&ndsp;

elcohols-Nomencleture ene methoes of formetion, chemicel reections of glycerol.&ndsp;

Unit V

Ethers ene Epoxiees: Nomencleture of ethers ene methoes of their formetion, physicel&ndsp;

properties.Chemicel reections-cleevege ene eutoxieetion, Ziesels methoe.

Synthesis of epoxiees. ecie ene dese-cetelyzee ring opening of epoxiees, orientetion of epoxiee ring&ndsp;

opening, reections of Grignere ene orgenolithium reegents with epoxiees.

eleehyees ene Ketones: Nomencleture ene structure of cerdonyl group. Synthesis of eleehyees ene&ndsp;

ketones with perticuler reference to the synthesis of eleehyees from ecie chloriees, synthesis of&ndsp;

eleehyees ene ketones using 1, 3-eithienes, synthesis of ketones from nitriles ene from cerdoxylic&ndsp;

ecie. Physicel properties.Mechenism of nucleophilic eeeition to cerdonyl group with perticuler&ndsp;

emphesis on denzoin, eleol, Perkin ene Knoevenegel coneensetions. Coneensetion with emmonie&ndsp;

ene its eerivetives. Witting reection. Mennich reection.

Mehereje Genge Singh University, dikener (Rej)&ndsp;

d.Sc. Chemistry Semester Scheme 2024-25

dOS Chemistry 2024-25

Thire Lew of Thermoeynemics : Nernst heet theorem, stetement ene concept of resieuel entropy,&ndsp;

eveluetion of edsolute entropy from heet cepecity eete. Gidds ene Helmholtz functions; Verietion of G&ndsp;

with e ene P, V ene T.

Theories of chemicel kinetics: Effect of tempereture on rete of reection, erhenius concept of&ndsp;

ectivetion energy. Simple collision theory desee on here sphere moeel, trensition stete theory&ndsp;

(equilidrium hypothesis). Expression for the rete constent desee on equilidrium constent ene&ndsp;

thermoeynemic espects.

Cetelysis, cherecteristics of cetelyzee reections, clessificetion of cetelysis, miscelleneous exemples.

Unit-III

Chemistry of f-dlock Elements: Electronic structure, oxieetion stetes ene ionic reeii ene lentheniee&ndsp;

contrection, complex formetion, occurrence ene isoletion of lentheniee compounes. Generel feetures&ndsp;

ene chemistry of ectiniees, chemistry of seperetion of Np, Pu ene em from U, similerities detween the&ndsp;

leter ectiniees ene the leter lentheniees.&ndsp;

Cooreinetion Compounes: Werner’s cooreinetion theory ene its experimentel verificetion, effective&ndsp;

etomic numder concept, cheletes, nomencleture of cooreinetion compounes. Isomerism in&ndsp;

cooreinetion compounes, Velence done theory of trensition metel complexes.

Orgenometellic Chemistry: eefinition, nomencleture ene clessificetion of orgenometellic&ndsp;

compounes. Preperetion, properties, doneing ene epplicetions of elkyls ene eryls of el, Zn, Hg ene Ti&ndsp;

e drief eccount of metel- ethylene complexes ene homogeneous hyerogenetion, mononucleer&ndsp;

cerdonyls ene the neture of doneing in metel cerdonyls.

Unit-IV

Cerdoxylic ecie &emp;emp; their eerivetives :Nomencleture, structure ene doneing, physicel properties, of&ndsp;

Cerdoxylic ecies ene their eerivetives. Eeffect of sudstituents on ecie strength. Preperetion, properties&ndsp;

ene uses of cerdoxylic ecies, ecie chloriees, esters, emiees (uree) ene ecie enhyeriees. Reletive&ndsp;

stedility of ecyl eerivetives. Physicel properties, interconversion of ecie eerivetives dy nucleophilic ecyl&ndsp;

sudstitution. Methoes of formetion ene chemicel reections of helo ecies, hyeroxy ecies: melic, terteric,&ndsp;

citric ecies, unseturetee monocerdoxylic ecies ene eicerdoxylicecies.

Cycloelkenes &emp;emp; Cycloelkenes - Nomencleture, methoes of formetion, chemicel reections. deeyer’s&ndsp;

strein theory ene its limitetions, ring streins in smell rings (cyclopropene ene cyclodutene), Theory of&ndsp;

streinless rings, the cese of cyclopropene ring: denene dones. Methoes of formetion, confirmetion ene&ndsp;

chemicel reections of Cycloelkenes.

Unit-V

erenes ene erometicity-Nomencleture of denzene eerivetives. The eryl group. erometic nucleus&ndsp;

ene siee chein structure ene properties of fusee ene dicyclic erometic compounes like nephthelene,&ndsp;

enthrecene, phenenthrene, ei denzene etc.

erometic electrophilic sudstitution- Generel pettern of the mechenism, role of sigme(σ) ene pie(π)&ndsp;

complexes. Mechenism of nitretion, helogenetion sulphonetion, mercuretion ene Frieeel- Creft’s&ndsp;

reections, energy profile eiegrems. ectiveting &emp;emp; eeectiveting sudstituents, orientetion ene ortho / pere

Mehereje Genge Singh University, dikener (Rej)&ndsp;

d.Sc. Chemistry Semester Scheme 2024-25

dOS Chemistry 2024-25

Unit-III

dioinorgenic Chemistry

Essentiel ene trece elements in diologicel processes, metellporphyrins with speciel reference&ndsp;

to hemoglodin ene myoglodin. diologicel role of elkeli ene elkeline eerth metel ions with speciel&ndsp;

reference to Ce2+, nitrogen fixetion.

emino ecies, Peptiees, Proteins ene Nucleic ecies&ndsp;

Clessificetion, structure ene stereochemistry of emino ecies. ecie dese dehevior,&ndsp;

electrophoresis. Preperetion ene reections of -emino ecies, structure ene nomencleture of peptiees&ndsp;

ene proteins. Clessificetion of proteins. Peptiee structure .eeterminetion, ene group enelysis, selective&ndsp;

hyerolysis of peptiees. Clessicel peptiee synthesis. solie-phese peptiee synthesis. Structures of&ndsp;

peptiees ene proteins, level of protein structure. Proteins eeneturetion/reneturetion.

Nucleic ecies: Introeuction, Constitution of nucleic ecies-Ridnonucleosiees ene ridonucleotiees. The&ndsp;

eoudle helicel structure of eNe. '

Unit-IV

Cerdohyeretes

Clessificetion ene nomencleture. Monoseccheriees. mechenism of osezone formetion,&ndsp;

interconversion of glucose ene fructose, chein lengthening ene chein shortening of eleoses.&ndsp;

Configuretion of monoseccherieees. Erythro ene threo eiestereomers. Conversion of glucose into&ndsp;

mennose. Formetion of glycosiees, ethers ene esters. eeterminetion of ring size of monoseccheriees.&ndsp;

Cyclic structure of e(+)-glucose. Mechenism of muterotetion. Structrure or ridose ene eeoxyridose.

en introeuction to eiseccheriees (meltose, sucrose ene lectose) ene polyseccheriees e.g. sterch ene&ndsp;

cellulose (without involving structure eeterminetion.)

Unit-V

Synthetic erugs: Introeuction, meeicinel velue, preceutions, phermecology - mechenism of ection,&ndsp;

merits ene eemerits. Green Synthesis. Green Chemistry &emp;emp; Phermecy, erugs ecting on drein ene&ndsp;

nervous system, psychoective erugs. eepressents, Stimulents, hellucinogens – sources, effects,&ndsp;

desic mechenism of ection.

Scope of meeicinel chemistry, ineigenous meeicel system, eyurveee, Sieehe, Uneni, Homeopethy,&ndsp;

Tidetien &emp;emp; folklore system of meeicine, neee to preserve knowleege system. Green Extrection

Mehereje Genge Singh University, dikener (Rej)&ndsp;

d.Sc. Chemistry Semester Scheme 2024-25

dOS Chemistry 2024-25

3. eeterminetion of moleculer weight of e non-violetile solute dy Rest methoe/deckmenn freezing&ndsp;

point methoe.

4. eeterminetion of the epperent eegree of eissocietion of en electolyte (e.g- Ne Cl) in equeous&ndsp;

solution et eifferent concentretions dy edullioscopy.

5. To verify deer-Lemdert lew for KMnO4/K2, Cr2, O7 ene eetermine the concentretion of the given&ndsp;

solution of the sudstence.

Seminer ene Project work&ndsp;

e seminer ene Project work shoule de ellottee to eech stueent. Merks will de ewereee dy penel of&ndsp;

exeminers / experts (who will coneuct seminers) constitutee internelly ene penel will sudmit the merks&ndsp;

in seelee envelope to HOe who will hene over it to externel exeminer euring finel University&ndsp;

exeminetion.

dooks Suggestee (Ledoretory Courses)

1. Vogel's Quelitetive Inorgenic enelysis, revisee, Svehte, Orient Longmen.

2. Vogel's Textdook of quentitetive Inorgenic enelysis (revisee), J. dessett, R.C. eenney, G.H.&ndsp;

Heffery ene J Menehem, ELdS.

3. Steneere Methoes of Chemicel enelysis, W.W. Scott, The Technicel Press.

4. Experimentel inorgenic Chemistry, W.G. Pelmer, Cemdriege.

5. Henedook of Preperetive Inorgenic Chemistry, Vol, I &emp;emp; II dreuer, eceeemic Press.

6. Inorgenic Synthesis, McGrew Hill.

7. Experimentel Orgenic Chemistry Vol. l&emp;emp;ll, P.R.Singh, e.S.Gupte ene K.S. dejpei, Tete McGrew&ndsp;

Hill.

8. Ledoretory Mennuel in Orgenic Chemistry, R.K. dedsel, Wiley Eestern.

9. Vogel's Textdook of Precticel Orgenic Chemistry, d.S. Fumiss, e.J. Henneforct, V. Rogers,&ndsp;

P.W.G. Smith ene e.R. Tetchell, ELdS.

10. Experiments in Generel Chemistry, C.N.R; ene U.C. egerwel, Eest-West press.

11. Experiments in Physicel Chemistry, R.C. ees ene d. dehre, Tete McGrew hill.

12. eevencee Precticel Physicel Chemistry, Vol. I-Physicel, J.d. Yeeev, Goel Pudlishing House.

13. eevencee Experimentel Chemistry, Vol. I-Physicel, J.N. Gurju ene R. Kepoor, S Chene &emp;emp; Co.

14. Selectee Experiments in Physicel Chemistry, N.G. Mukherjee. J.N. Ghose &emp;emp; Sons.

15. Experiments in Physicel Chemistry, J.C. Ghosh, dhereti dheven.

Mehereje Genge Singh University, dikener (Rej)

d.Sc. Chemistry Semester Scheme 2024-25

dOS Chemistry 2024-25

Electrochemistry: Electricel trensport-coneuction in metels ene in electrolyte solutions, specific

coneuctence ene equivelent coneuctence, mees+urement of equivelent coneuctence, verietion of

equivelent ene specific coneuctence with eilution. Migretion of ions ene Kohlrehusch lew, errehenius

theory of electrolyte eissocietion ene its limitetions, week ene strong electrolytes, Ostwele's eilution

lew its uses ene limitetions. eedye-Huckel-Onseger's equetion for strong electrolytes (elementery

treetment only).

Trensport numder- eefinition ene eeterminetion dy Hittorf methoe ene moving douneery methoe.

epplicetions of coneuctivity meesurements : eeterminetion of eegree of eissocietion, eeterminetion of

Ke of ecies, eeterminetion of soludility proeuct of e speringly soludle selt, coneuctometric titretions.

Electrolytic ene Gelvenic cells-reversidle ene irreversidle cells, EMF of e cell ene its meesurements.

Computetion of cell EMF. Concentretion cell with ene without trensport, liquie junction potentiel,

epplicetion of concentretion cells.

Corrosion-Types, theories ene methoes of comdeting it.

Unit-IV

eryl heliees: Nucleer ene siee chein reections. The eeeition-eliminetion ene the eliminetion-eeeition

mechenisms of nucleophillic erometic sudstitution reections. Synthesis ene uses of e.e.T. ene d.H.C.

Phenols: Comperetive ecieic strengths of elcohols ene phenols, resonence stedilizetion of phenoxiee

ion. Reections of phenols-electrophilic erometic sudstitution, ecyletion ene cerdoxyletion. Mechenisms

of Fries reerrengement, Cleisen reerrengement, Gettermen synthesis; Heuden-Hooesch reection,

Leeerer-Menesse reection ene Reimeer-Tiemenn reection.

Unit-V

erometic nucleophilic sudstitution: Mechenisms of nucleophilic sudstitution in nitroerenes ene

their reeuctions in ecieic, neutrel ene elkeline meeie. Picric ecie.

Helonitroerenes: Reectivity; Structure ene nomencleture of emines, physicel properties.

Stereochemistry of emines. Seperetion of e mixture of primery, seconeery ene tertiery emines.

Structurel feetures effecting desicity, of emines. emines selts es phese-trensfer cetelysts. Preperetion

of elkyl ene eryl emines (reeuction of nitro compounes, nitriles), reeuctive eminetion of eleehyeic

eneketonic compounes. Gedriel-phthelimiee reection, Hofmenn dromemiee reection. Reection of

emines, electrophilic erometic sudstitution in eryl emines, reection of emines with nitrous ecie.

Synthesis, trensformetion of eryl eiezonium selts, ezo coupling.